ANALISIS PARAMETER NILAI DIFUSIVITAS KAFEIN PADA EKSTRAKSI AMPAS KOPI BERBANTU GELOMBANG ULTRASONIK

Penulis

  • Mega Mustikaningrum Universitas Muhammadiyah Gresik
  • Fikrah Dian Indrawati Sawali Program Studi Teknik Kimia Mineral, Politeknik Industri Logam Morowali

DOI:

https://doi.org/10.61844/jtkm.v2i1.448

Kata Kunci:

Ampas kopi, Kafein, Ultrasonik, Difusivitas, Konstanta kecepatan ekstraksi

Abstrak

Limbah ampas kopi yang sangat melimpah diakibatkan konsumsi minuman kopi yang meningkat dan menjadi gagasan penting bagaimana pengolahan limbah ampas kopi agar kemudian tidak menjadi limbah buangan yang tidak bermanfaat. Salah satu senyawa yang dapat dimanfaatkan kembali dari buangan limbah ampas kopi adalah kafein. Kafein merupakan senyawa yang bermanfaat bagi kesehatan. Kafein dapat di isolasi dari limbah ampas kopi dengan cara ekstraksi. Pada penelitian ini ekstraksi dilakukan dengan menggunakan bantuan gelombang ultrasonik dengan bantuan alat sonikator tipe bath. Sebesar 25 gram sampel ampas kopi dilarutkan pada 250 ml dan diletakan pada alat sonikator yang dioperasikan selama 45 menit pada 30 0C. Sampel hasil kemudian dianalisis menggunakan HPLC untuk mengetahui konsentrasi akhir kafein yang dihasilkan. Fokus penelitian ini adalah mencari nilai beberapa parameter uji seperti konstanta difusivitas (DA), konstanta kecepatan ekstraksi (k) dan konstanta kesetimbangan ekstraksi (K), dimana didapatkan masing-masing nilai parameter uji sebesar 0.014462 dm2/menit; 0,00256 dm/menit dan 103,218. Konsentrasi akhir kafein yang dihasilkan pada penelitian sebesar 0,08053 mol/dm3.

Unduhan

Data unduhan belum tersedia.

Referensi

F. Girotto, A. Pivato, R. Cossu, G. E. Nkeng and M. C. Lavagnolo, "The broad spectrum of possibilities for spent coffee grounds valorisation," Journal of Material Cycles and Waste Management , vol. 20, p. 695–701, 2018.

P. S. Murthy and M. M. Naidu, "Sustainable management of coffee industry by-products and value addition—A review," Resources, Conservation and Recycling, vol. 66, pp. 45-58, 2012.

ICO, "ICO Trade Statistics Tables; International Coffee Organization (ICO)," http://www.ico.org/trade_statistics.asp, London, UK, 2021.

U. F. A. Service and U. D. o. Agriculture, "USDA Coffee: World Markets and Trade," https://www.fas.usda.gov/data/coffee-world-markets-and-trade, 2021.

R. Campos-Vega, G. Loarca-Piña, H. A. Vergara-Castañeda and B. D. Oomah, "Spent coffee grounds: A review on current research and future prospects," Trends in Food Science & Technology, vol. 45, no. 1, pp. 24-36, 2015.

M. Stylianou, A. Agapiou, M. Omirou, I. Vyrides, I. M. Ioannides, G. Maratheftis and D. Fasoula, "Converting environmental risks to benefits by using spent coffee grounds (SCG) as a valuable resource," Environmental Science and Pollution Research, vol. 25, no. 36, pp. 35776-35790., 2018 .

T. M. Mata, A. A. Martins and N. S. Caetano, "Bio-refinery approach for spent coffee grounds valorization," Bioresource Technology, vol. 247, pp. 1077-1084, 2018.

E. Commission, "EC The Waste Framework Directive 2008/98/EC;," European Commission, Luxembourg, 2008.

A. A. Martins, M. Simaria, J. Barbosa, R. Barbosa, D. T. Silva, C. S. Rocha, T. M. Mata and N. S. Caetano, "Life cycle assessment tool of electricity generation in Portugal," Environment, Development and Sustainability , vol. 20, p. 129–143, 2018.

N. S. Caetano, V. F. M. Silva, A. C. Melo, A. A. Martins and T. M. Mata, "Spent coffee grounds for biodiesel production and other applications," Clean Technologies and Environmental Policy, vol. 16, p. 1423–1430, 2014.

N. S. Caetano, T. M. Mata, A. A. Martins and M. C. Felgueiras, "New Trends in Energy Production and Utilization," Energy Procedia, vol. 107, pp. 7-14, 2017.

H. Ribeiro, J. Marto, S. Raposo, M. Agapito, V. Isaac, B. G. Chiari, P. F. Lisboa, A. Paiva, S. Barreiros and P. Simões, "From coffee industry waste materials to skin-friendly products with improved skin fat levels," European Journal of Lipid Science and Technology, vol. 115, no. 3, pp. 330-336, 2012.

G. D. Saratale, R. Bhosale, S. Shobana, J. R. Banu, A. Pugazhendhi, E. Mahmoud, R. Sirohi, S. K. Bhatia, A. Atabani, V. Mulone, J.-J. Yoon, H. S. Shin and G. Kumar, "A review on valorization of spent coffee grounds (SCG) towards biopolymers and biocatalysts production," Bioresource Technology, vol. 314, p. 123800, 2020.

M. M. Ali, M. Eisa and M. I. Taha, "Determination of Caffeine in Some Sudanase Benerages by High Performance Liquid Chromatography," Pakistan Journal of Nutrition , vol. 11, no. 4, pp. 336-342, 2012.

M. Soni, "Extraction and analysis of Caffeine from various brands of tea leaves marketed in India," Journal of Pharmacognosy and Phytochemistry, vol. 8, no. 1, pp. 119-120, 2019.

M. Grassia, G. Salvatori, M. Roberti, D. Planeta and L. Cinquanta, "Polyphenols, methylxanthines, fatty acids and minerals in cocoa beans and cocoa products," Journal of Food Measurement and Characterization, vol. 13, p. 1721–1728, 2019.

U. Umeda and Y. T. Puyate, "Extraction of Caffeine from Native Kola-nut (cola - acuminate)," International Journal of Chemistry and Chemical Processes, vol. 6, no. 1, pp. 47-55, 2020.

R. M. v. Dam, F. B. Hu and W. C. Willett, "Coffee, Caffeine, and Health," The New England Journal of Medicine, vol. 383, no. 4, pp. 369-378, 2020.

K. F.Alsamarrai and S. T. Ameen, "Simultaneous Ratio Derivative Spectrophotometric Determination of Paracetamol, Caffeine and Ibuprofen in Their Ternary Form," Baghdad Science Journal, vol. 19, no. 6, pp. 1276-1285, 2022.

J. Monteiro, M. G. Alves, P. F. Oliveira and B. M. Silva, "Pharmacological potential of methylxanthines: Retrospective analysis and future expectations," Critical Reviews in Food Science and Nutrition, pp. 1-29, 2018.

G. Grosso, J. Godos, F. Galvano and E. L. Giovannucci, "Coffee, Caffeine, and Health," Annual Review of Nutrition, vol. 37, no. 1, pp. 131-156, 2017.

J. Aaseth, P. Dusek and P. M. Roos, "Prevention of progression in Parkinson's disease," Biometals, vol. 31, no. 5, pp. 737-747, 2018.

T. Wolde, "Effects of caffeine on health and nutrition: A Review," Food Science and Quality Management, vol. 30, pp. 59-65, 2014.

B. Han, J. Chen, Y.-q. Yu, Y.-b. Cao and Y.-y. Jiang, "Antifungal activity of Rubus chingii extract combined with fluconazole against fluconazole-resistant Candida albicans," Microbiology and Immunology, vol. 60, p. 82–92, 2016.

L. S. Torres-Valenzuela, A. Ballesteros-Gómez, A. Sanin and S. Rubio, "Valorization of spent coffee grounds by supramolecular solvent extraction," Separation and Purification Technology, vol. 228, p. 115759, 2019.

K. S. Andrade, R. T. Gonçalvez, M. Maraschin, R. M. Ribeiro-do-Valle, J. Martínez and S. R. Ferreira, "Supercritical fluid extraction from spent coffee grounds and coffee husks: Antioxidant activity and effect of operational variables on extract composition," Talanta, vol. 88, pp. 544-552, 2012.

M. D. Pavlović, A. V. Buntić, S. S. Šiler-Marinković and S. I. Dimitrijević-Branković, "Ethanol influenced fast microwave-assisted extraction for natural antioxidants obtaining from spent filter coffee," Separation and Purification Technology, vol. 118, pp. 503-510, 2013.

Z. Zhang, M. M. Poojary, A. Choudhary, D. K. Rai, M. N. Lund and B. K. Tiwari, "Ultrasound processing of coffee silver skin, brewer's spent grain and potato peel wastes for phenolic compounds and amino acids: a comparative study," Journal of Food Science and Technology, 2020.

G. R. Lopes, C. P. Passos, C. Rodrigues, J. A. Teixeira and M. A. Coimbra, "Impact of microwave-assisted extraction on roasted coffee carbohydrates, caffeine, chlorogenic acids and coloured compounds," Food Research International, vol. 129, p. 108864, 2020.

A. M. Ferreira, H. M. D. Gomes, J. A. P. Coutinho and M. G. Freire, "Valorization of Spent Coffee by Caffeine Extraction Using Aqueous Solutions of Cholinium-Based Ionic Liquids," Sustainability, vol. 13, p. 7509, 2021.

B. A. Abdul-Majeed, A. A. Hassan and B. M. Kurji, "Extraction of Oil from Eucalyptus Camadulensis Using Water Distillation Method," Iraqi Journal of Chemical and Petroleum Engineering, vol. 14, no. 2, pp. 7-12, 2013.

S. A. Mohammed and M. S. Hameed, "Extraction of 4-Nitrophenol from Aqueous Solutions using Bulk ionic Liquid Membranes," International Journal of Current Engineering and Technology, vol. 6, no. 2, pp. 542-550, 2016.

F. Chemat, N. Rombaut, A.-G. Sicaire, A. Meullemiestre, A.-S. Fabiano-Tixier and M. Abert-Vian, "Ultrasound assisted extraction of food and natural products. Mechanisms, techniques, combinations, protocols and applications. A review," Ultrasonics Sonochemistry, vol. 34, pp. 540-560, 2017.

A. M. Al-Yaqoobi, M. N. Al-Rikabey and K. H. Algharrawi, "Treatment of Dairy Wastewater by ELectrocoagulation and Ultrasonic - Assisted Electrocoagulation Methods," Environmental Engineering and Management Journal, vol. 20, no. 6, pp. 949-957, 2021.

D. Beverly, E. Lopez-Quiroga, R. Farr, J. Melrose, S. Henson, S. Bakalis and P. J. Fryer, "Modeling Mass and Heat Transfer in Multiphase Coffee Aroma," Industrial & Engineering Chemistry Research , vol. 59, no. 24, pp. 11099-11112, 2020.

B. Corrochano, J. Melrose, A. Bentley, P. Fryer and S. Bakalis, "A new methodology to estimate the steady-state permeability of roast and ground coffee in packed beds," Journal of Food Engineering, vol. 150, pp. 106-116, 2015.

Unduhan

Diterbitkan

2023-06-29

Cara Mengutip

[1]
M. Mustikaningrum dan F. D. I. Sawali, “ANALISIS PARAMETER NILAI DIFUSIVITAS KAFEIN PADA EKSTRAKSI AMPAS KOPI BERBANTU GELOMBANG ULTRASONIK”, JTKM, vol. 2, no. 1, hlm. 1–6, Jun 2023.